Mold, found on old or unrefrigerated bread, comes from fungi,  one of the most ubiquitous and successful forms of life on the planet.   There are dozens of thousands of species, which can be found  practically everywhere.  Scientists who study fungi, called mycologists,  tell say that approximately one out of every 20 living species is a  form of fungus.
Fungi cannot receive energy directly from the sun because they do not have chlorophyll, and must therefore live off other plants and animals.  Some fungi are parasites, actively attacking a host for nutrients.   Most, however, are scavengers, turning organic matter into soil.   Without fungi, many plants would die, because they require rich soil to  thrive.
Most fungi tend to be flexible about their food choices.   They feed on a wide variety of organic molecules, and their flexibility  is largely responsible for their ubiquity.  Fungi produce dozens of digestive enzymes and acids, which they secrete into a material as they grow over it. 
Unlike humans, mold digests first, then eats, rather than  vice versa.  Under the right conditions, there exist forms of fungi that  eat practically anything but metal.  Special fungi produced through  selective breeding are sometimes used as agents to target specific  compounds for cleanup. 
Fungi reproduce exponentially until all available nutrients are  exhausted.  Some forms of mold can double their mass every hour.  They  reproduce by means of spores, tiny vectors which are produced by the  fungus en masse.  Spores are extremely small and numerous — there are  probably millions of fungal spores in any room at one time. 
Luckily, these spores can be destroyed by cooking, which is why bread  doesn't immediately get infected with mold.  Over time, however,  airborne spores find their way onto the nutrient-rich surface of bread  and start multiplying — even under the cold conditions of a  refrigerator.  At freezing point, fungi become dormant.  If they are  exposed to heat again, they can revive and continue to grow.
 


